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On corrosion to stainless steel by calcium chloride with different extender

Lv XU, Yuanyang HU, Liwei WANG, Ruzhu WANG,

《能源前沿（英文）》 2010年第4卷第2期页码 181-184 doi: 10.1007/s11708-009-0065-2

摘要： A calcium chloride solution with a different extender, which is made up of either pure calcium chloride, calcium chloride with expanded graphite, or calcium chloride with activated carbon, acts differently on stainless steel. The mass ratio between calcium chloride with expanded graphite or activated carbon is almost 4∶1, which is demonstrated to be the optimum ratio. The experimental research in this paper reveals that, of the three solutions, which are pure calcium chloride, calcium chloride with expanded graphite, and calcium chloride with activated carbon, the strongest oxidation creation and pitting corrosion happened in the solution of calcium chloride with expanded graphite, the weakest oxidation creation happened in the solution of calcium chloride with activated carbon, and pitting corrosion was stronger than oxidation creation in the solution of pure calcium chloride. This paper gives the reasons for these phenomena. Furthermore, based on theory analysis, multiple means and approaches are provided to prevent stainless steel from further corroding.

关键词： stainless steel corrosion calcium chloride expanded graphite activated carbon oxidation creation pitting corrosion

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Structure creation in earthen construction materials: information from dry soil mixtures

Christopher BECKETT, Charles AUGARDE

《结构与土木工程前沿（英文）》 2011年第5卷第2期页码 151-159 doi: 10.1007/s11709-011-0109-7

摘要： There is increasing interest in the use of earthen construction materials, such as rammed earth, due to their inherent sustainability. These materials have been used by man for thousands of years and some of the earliest examples can be found in China. Features of the structures of these materials arise from the means of production. In particular, in situ earthen construction materials exhibit strong anisotropy due to their layered nature. A more subtle structure effect arises from the way that the earth mixture is deposited. This paper reviews and discusses stratification effects in dry soil mixtures, including some original experimental work, and indicates some links between the features of the dry mixtures and earthen construction materials. Improved understanding of the physical processes in play will allow more accurate specification of these materials in the future, and hence spread their use.

关键词： rammed earth stratification particle size distribution pore size distribution

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Self-propelled automatic chassis of Lunokhod-1: History of creation in episodes

Mikhail MALENKOV

《机械工程前沿（英文）》 2016年第11卷第1期页码 60-86 doi: 10.1007/s11465-016-0370-5

摘要：

This report reviews the most important episodes in the history of designing the self-propelled automatic chassis of the first mobile extraterrestrial vehicle in the world, Lunokhod-1. The review considers the issues in designing moon rovers, their essential features, and the particular construction properties of their systems, mechanisms, units, and assemblies. It presents the results of exploiting the chassis of Lunokhod-1 and Lunokhod-2. Analysis of the approaches utilized and engineering solutions reveals their value as well as the consequences of certain defects.

关键词： moon rover self-propelled chassis propulsion wheel suspension soil properties cross-country ability

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中央企业应该也能够率先成为自主创新的主体

顾大钊

《中国工程科学》 2008年第10卷第10期页码 9-13

摘要：

系统分析了中央企业在我国经济中的地位和作用、中央企业本身技术需求、经济实力、科技资源和成果转化特点，指出中央企业应该也能够率先成为自主创新的主体。而要实现这一目标，必须充分调动企业、企业科技管理人员和企业研发人员技术创新的积极性，结合神华的成功经验，提出了企业基于技术资源整合成为自主创新主体的新模式。

关键词：中央企业技术创新资源整合

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Integration of VR with BIM to facilitate real-time creation of bill of quantities during the design phase

Jordan DAVIDSON, John FOWLER, Charalampos PANTAZIS, Massimo SANNINO, Jordan WALKER, Moslem SHEIKHKHOSHKAR, Farzad Pour RAHIMIAN

《工程管理前沿（英文）》 2020年第7卷第3期页码 396-403 doi: 10.1007/s42524-019-0039-y

摘要： As building practices change, procedures that seemed indispensable at one point can be abandoned for others, one example of which is the bill of quantities (B/Q). Research into the extant literature attributes the declining use of B/Qs to a multitude of reasons, such as its complexity, the potentially long time required to produce it, the growth in popularity of non-traditional procurement systems, and the challenge of using the information within the document in a construction schedule. With these issues in mind, building information modeling (BIM) and virtual reality (VR) are combined and proposed as a potential solution that allows inclusion of the client into the design process. Following a literature review and precedent study, an experiment was carried out using this new process to simulate a client’s design decisions on window and interior furnishings. The choices made by the client using VR automatically updated a B/Q schedule built in Revit and allowed them to have a firm understanding of project costs. Besides giving the client more confidence in a pleasing final outcome, the technology also ensured an up-to-date, accurate, and easily understandable B/Q. The proposed method features great potential savings in cost and time and gives the B/Q a newfound importance in future construction processes. The research case presented in this paper is a stepping stone in exploring new opportunities offered by VR and BIM and how they could improve the reliability and accuracy of traditional procurement within construction, specifically within the B/Q document.

关键词： virtual reality bill of quantities BIM Revit real-time synchronisation

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Inheritance and Innovation of Engineering Management Informatization

Kai Sun,Ren-huai Liu

《工程管理前沿（英文）》 2014年第1卷第1期页码 76-82 doi: 10.15302/J-FEM-2014014

摘要： In the life-cycle of large projects, the operational phase lasts the longest, costs the most and substantially benefits the project. During the whole phase, energy, material and human resources may cost a lot. Effective control of such costs is one of the main targets of engineering management informatization. How to lower the organization collaboration cost in project management and how to support effective collaboration among different areas, organizations and departments in the ways of technology and management are major goals in engineering management informatization. In the phase of project operation, project owners, partners and customers are the stakeholders of engineering management informatization. Through the case of airport management informatization, inherited and innovation of engineering management informatization will be discussed. It is illustrated that airport informatization is the innovation of business model and technology applications through the analysis and study on cases of airport informatization.

关键词： engineering management informatization inter-organizational relationship management creation resource sharing

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论创造性思维

冯国瑞

《中国工程科学》 2004年第6卷第6期页码 15-21

摘要：

文章首先阐明了创新与创造的联系与区别，然后重点论述了创造性思维的界定、创造性思维的运演机制、创造性思维的重大意义以及全面提高思维主体综合素质等问题。

关键词：创新创造创造性思维思维主体思维客体

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Phenolic compounds removal by wet air oxidation based processes

Linbi Zhou, Hongbin Cao, Claude Descorme, Yongbing Xie

《环境科学与工程前沿（英文）》 2018年第12卷第1期 doi: 10.1007/s11783-017-0970-2

摘要： Wet air oxidation (WAO) and catalytic wet air oxidation (CWAO) are efficient processes to degrade organic pollutants in water. In this paper, we especially reviewed the WAO and CWAO processes for phenolic compounds degradation. It provides a comprehensive introduction to the CWAO processes that could be beneficial to the scientists entering this field of research. The influence of different reaction parameters, such as temperature, oxygen pressure, pH, stirring speed are analyzed in detail; Homogenous catalysts and heterogeneous catalysts including carbon materials, transitional metal oxides and noble metals are extensively discussed, among which Cu based catalysts and Ru catalysts were shown to be the most active. Three different kinds of the reactor implemented for the CWAO (autoclave, packed bed and membrane reactors) are illustrated and compared. To enhance the degradation efficiency and reduce the cost of the CWAO process, biological degradation can be combined to develop an integrated technology.

关键词： Wet air oxidation Catalytic wet air oxidation Phenolic compounds Heterogeneous catalysts Mechanism

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β-Cyclodextrin promoted oxidation of primary amines to nitriles in water

Dongpo SHI, Hongbing JI, Zhong LI

《化学科学与工程前沿（英文）》 2009年第3卷第2期页码 196-200 doi: 10.1007/s11705-009-0051-6

摘要： A facile, efficient and substrate-selective oxidation of the primary amines with NaClO as oxidant catalyzed by cyclodextrin ( CD) has been developed in water for the first time, and the behavior of cyclodextrin that catalyzed the primary amines to nitriles in water was investigated. It was found that the primary amines which could form host-guest complexes with cyclodextrin were oxidized to nitriles with excellent yields at ambient temperature. The results show that cyclodextrin worked not only as a solubilizing agent but also as a catalyst in these reactions.

关键词： substrate-selective amines oxidation β-cyclodextrin

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Solvent-free mechanochemical mild oxidation method to enhance adsorption properties of chitosan

《环境科学与工程前沿（英文）》 2021年第15卷第6期 doi: 10.1007/s11783-021-1416-4

摘要：

• Solvent-free chitosan oxidation is obtained by rapid mechanochemical reaction.

关键词： Chitosan High energy ball milling Mechanochemistry Oxidation

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Plasma-assisted oxidation of benzoic acid

Anna Khlyustova, Nikolay Sirotkin

《化学科学与工程前沿（英文）》 2020年第14卷第4期页码 513-521 doi: 10.1007/s11705-019-1825-0

摘要： Plasma-assisted oxidation of organic compounds is one of the developing technologies for wastewater treatment. Plasmas effectively accelerate degradation processes due to plasma generated reactive species and ultra-violet radiation. Oxidation of benzoic acid in aqueous solutions by the atmospheric pressure glow discharge and underwater diaphragm discharge was studied and monitored by fluorescence and spectrophotometric methods. Discharge type and solution pH affect the formation rates of mono- and dihydroxybenzoic acids. Dihydroxyl derivatives were formed only by glow discharge action. The yields of hydroxyl radical were estimated on the kinetics data for the hydroxylation of benzoic acid. The steps of the hydroxylation processes and further oxidation were described.

关键词： atmospheric pressure glow discharge underwater diaphragm discharge oxidation benzoic acid hydroxyl radical

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Novel coprecipitation–oxidation method for recovering iron from steel waste pickling liquor

Shejiang Liu, Hongyang Yang, Yongkui Yang, Yupeng Guo, Yun Qi

《环境科学与工程前沿（英文）》 2017年第11卷第1期 doi: 10.1007/s11783-017-0902-1

摘要： Coprecipitation–oxidation method was developed to recover the iron from wastewater. Fe O nanoparticles were well synthesized from steel waste pickling liquor. Promoters greatly improved the properties of synthesized Fe O nanoparticle. Real-time control of the Fe /Fe molar ratio was achieved by ORP monitoring. Waste pickling liquors (WPLs) containing high concentrations of iron and acid are hazardous waste products from the steel pickling processes. A novel combined coprecipitation–oxidation method for iron recovery by Fe O nanoparticle production from the WPLs was developed in this study. An oxidation–reduction potential monitoring method was developed for real-time control of the Fe /Fe molar ratio. The key coprecipitation–oxidation parameters were determined using the orthogonal experimental design method. The use of promoters greatly improved the Fe O nanoparticle crystallinity, size, magnetization, and dispersion. X-ray diffraction patterns showed that the produced Fe O nanoparticles were single phase. The Fe O nanoparticles were approximately spherical and slightly agglomerated. Vibrating sample magnetometry showed that the Fe O nanoparticles produced from the WPLs had good magnetic properties, with a saturation magnetization of 80.206 emu·g and a remanence of 10.500 emu·g . The results show that this novel coprecipitation–oxidation method has great potential for recycling iron in WPLs.

关键词： Waste pickling liquor Coprecipitation–oxidation Fe₃O₄ nanoparticles Oxidation–reduction potential Promoter

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Electricity-driven ammonia oxidation and acetate production in microbial electrosynthesis systems

《环境科学与工程前沿（英文）》 2022年第16卷第4期 doi: 10.1007/s11783-021-1476-5

摘要：

• MES was constructed for simultaneous ammonia removal and acetate production.

关键词： Biocathode Carbon dioxide Electrochemical oxidation Graphite anode Boron-doped diamond

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Application of permanganate in the oxidation of micropollutants: a mini review

Xiaohong GUAN, Di HE, Jun MA, Guanghao CHEN

《环境科学与工程前沿（英文）》 2010年第4卷第4期页码 405-413 doi: 10.1007/s11783-010-0252-8

摘要： As a green oxidant, permanganate has received considerable attention for the removal of micropollutants in drinking water treatment. To provide a better understanding of the oxidation of organic micropollutants with permanganate, the oxidation kinetics of 32 micropollutants were compiled. The pollutants include algal toxins, endocrine disrupting chemicals (EDCs), and pharmaceuticals. The oxidation kinetics of micropollutants by permanganate were found to be first order with respect to both contaminant and permanganate concentrations from which second-order rate constants ( ″) were obtained. Permanganate oxidized the heterocyclic aromatics with vinyl moiety (i.e., microcystins, carbamazepine, and dichlorvos) by the addition of double bonds. For the polycyclic aromatic hydrocarbons (PAHs) with alkyl groups, permanganate attacked the benzylic C-H through abstraction of hydrogen. The mechanism for the oxidation of phenolic EDCs by permanganate was a single electron transfer and aromatic ring cleavage. The presence of background matrices could enhance the oxidation of some phenolic EDCs by permanganate, including phenol, chlorinated phenols, bisphenol A, and trichlosan. The toxicity of dichlorvos solution increased after permanganate oxidation, and the estrogenic activity of bisphnol A/estrone increased significantly at the beginning of permanganate oxidation. Therefore, the toxicity of degradation products or intermediates should be determined in the permanganate oxidation processes to better evaluate the applicability of permanganate. The influence of background ions on the permanganate oxidation process is far from clear and should be elucidated in the future studies to better predict the performance of permanganate oxidation of micropollutants. Moreover, methods should be employed to catalyze the permanganate oxidation process to achieve better removal of micropollutants.

关键词： pharmaceuticals endocrine disrupting chemicals (EDCs) algal toxins permanganate oxidation

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“ALL FREE” — a novel design concept of applying partial oxidation process to vehicle

Ling LIN, Wenshuang LIN, Qingbiao LI, Yao ZHOU,

《化学科学与工程前沿（英文）》 2010年第4卷第2期页码 207-212 doi: 10.1007/s11705-009-0240-3

摘要： With the rapid expansion of the global motor vehicle population, the transportation sector has taken up a growing proportion among all the carbon dioxide emission-related sectors. To contribute to solutions of the carbon dioxide-oriented problem in transportation, this paper proposes the “ALL FREE” concept that applies partial oxidation process instead of the conventional complete oxidation to vehicle engines. In such an engine, the fuels are partially oxidized into corresponding chemical products, which, as a result, enable the process to be theoretically free of CO, while the heat output of the partial oxidation could drive the vehicle. On the other hand, the resulting products are of great value, which could decrease or even counteract the cost of fuels in transportation. In this paper, the thermodynamic and kinetic data (e.g., the heat output and heat release rate) of five selected partial oxidation reactions were calculated at length to demonstrate and exemplify the theoretical feasibility of the “ALL FREE” concept. It turned out that the partial oxidation of -butane to maleic anhydride has the most potential to meet the basic requirements of this concept. To sum up, this design concept is of significant application potential for the reduction of CO emissions in the transportation industry, although there remain many technical challenges.

关键词： oxidation process CO complete oxidation ALL FREE -butane